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Chem Commun (Camb). 2014 Apr 14;50(29):3802-5. doi: 10.1039/c4cc00275j. Epub 2014 Mar 3.

Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones.

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  • 1Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China. tiansk@ustc.edu.cn.

Abstract

A range of highly enantioenriched primary allylic amines underwent palladium-catalyzed oxidative coupling with sulfonyl hydrazides open to air at room temperature to give structurally diverse allylic sulfones in moderate to excellent yields with excellent retention of ee.

PMID:
24584133
[PubMed - indexed for MEDLINE]
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