Enhancing catalytic performance of Au catalysts by noncovalent functionalized graphene using functional ionic liquids

J Hazard Mater. 2014 Apr 15:270:11-7. doi: 10.1016/j.jhazmat.2014.01.033. Epub 2014 Jan 26.

Abstract

New catalyst, prepared through Au nanoparticles anchored on the Ionic Liquid of 3,4,9,10-perylene tetracarboxylic acid-noncovalent functionalized graphene (Au/PDIL-GS), was fabricated using a facile and environment-friendly approach. The information of the morphologies, sizes, dispersion of Au nanoparticles (NPs) and chemical composition for the as-prepared catalysts was verified by systematic characterizations, including transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), Raman spectra, X-ray diffraction (XRD) and X-Ray photoelectron spectroscopy (XPS). As a new catalyst, the resulting Au/PDIL-GS exhibited excellent catalytic activity in the reduction of 4-nitrophenol because of the synergistic effect between the PDIL-GS and Au NPs. The facile and environment-friendly approach provides a green way to effectively synthesize low cost Au-based catalysts for 4-NP reduction and is promising for the development of other useful materials.

Keywords: 3,4,9,10-Perylene tetracarboxylic acid; Au nanoparticles; Ionic liquid; Noncovalent functionalized grapheme; Supported catalyst.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Gold / chemistry*
  • Graphite / chemistry*
  • Green Chemistry Technology
  • Ionic Liquids / chemistry*
  • Metal Nanoparticles / chemistry*
  • Nitrophenols / chemistry
  • Oxidation-Reduction
  • Perylene / analogs & derivatives*
  • Perylene / chemistry
  • Waste Disposal, Fluid / methods
  • Water Pollutants, Chemical / chemistry

Substances

  • 3,4,9,10-perylene tetracarboxylic acid
  • Ionic Liquids
  • Nitrophenols
  • Water Pollutants, Chemical
  • Perylene
  • Gold
  • Graphite
  • 4-nitrophenol