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Chem Commun (Camb). 2014 Mar 14;50(21):2775-7. doi: 10.1039/c4cc00088a.

MeOTf-induced carboannulation of arylnitriles and aromatic alkynes: a new metal-free strategy to construct indenones.

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  • 1Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China. cjxi@tsinghua.edu.cn.

Abstract

MeOTf-induced carboannulation of arylnitriles and aromatic alkynes for synthesis of indenones under metal-free conditions has been described. When ortho-substituted benzonitriles were used, indeno[1,2-c]isoquinolines were formed.

PMID:
24480994
[PubMed - indexed for MEDLINE]
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