Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex

Chem Commun (Camb). 2014 Mar 7;50(19):2420-3. doi: 10.1039/c3cc48869a. Epub 2014 Jan 9.

Abstract

X-ray analysis of the gold cyclopropyl(methoxy)carbene complex [(P)AuC(OMe)(c-Pr)](+) SbF6(-) [P = P(t-Bu)2o-biphenyl] and comparison to extant protonated cyclopropyl ketones indicates that electron donation from the (P)Au fragment to the electron-deficient C1 atom is similar to that provided by a cyclopropyl group.