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Chemphyschem. 2014 Jan 13;15(1):85-9. doi: 10.1002/cphc.201300809. Epub 2013 Nov 27.

Poly(ethylene glycol) stabilized mesoporous metal-organic framework nanocrystals: efficient and durable catalysts for the oxidation of benzyl alcohol.

Author information

  • 1Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid and Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences (China); Department of Chemistry, Renmin University of China (China).

Abstract

Active, selective, and stable: The fabrication of uniform mesoporous Cu3(BTC)2 (BTC: 1,3,5-benzenetricarboxylate) nanocrystals with tunable size and porosity is reported. The as-synthesized Cu3(BTC)2 structures show high activity, selectivity, and stability for the aerobic oxidation of benzyl alcohol to aldehyde.

Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KEYWORDS:

alcohol oxidation; catalysts; mesoporous materials; metal-organic frameworks; nanocrystals

PMID:
24285509
[PubMed]
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