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Inorg Chem. 2013 Nov 4;52(21):12311-3. doi: 10.1021/ic401571h. Epub 2013 Oct 11.

Measurement of the Md3+/Md2+ reduction potential studied with flow electrolytic chromatography.

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  • 1Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195, Japan.

Abstract

The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md(3+) is reduced to Md(2+). The reduction potential of the Md(3+) + e(-) → Md(2+) couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.

PMID:
24116851
[PubMed]
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