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Chem Commun (Camb). 2013 Oct 3;49(86):10190-2. doi: 10.1039/c3cc45583a.

Palladium-catalyzed insertion of α,β-unsaturated N-tosylhydrazones and trapping with carbon nucleophiles.

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  • 1State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China. liangym@lzu.edu.cn.

Abstract

Palladium-catalyzed carbene migratory insertion-cyclization reactions were reported, delivering dihydronaphthalene and indene derivatives in moderate to good yields. A three-component cross-coupling was also developed. The reactions are easy to handle, under mild conditions and various functional groups are tolerated.

PMID:
24056675
[PubMed - indexed for MEDLINE]
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