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Chem Commun (Camb). 2013 Oct 3;49(86):10124-6. doi: 10.1039/c3cc44898c.

Controlled homopolymerization of multi-vinyl monomers: dendritic polymers synthesized via an optimized ATRA reaction.

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  • 1Network of Excellence for Functional Biomaterials, National University of Ireland, Galway, Ireland.


In this study, we have managed to find the optimal ATRA system that can obtain the highest mono-adduct yields with the purpose of minimizing the chain growth of divinyl monomers. The most highly hyperbranched polymers have been synthesized by the homopolymerization of multi-vinyl monomers via ATRA reaction.

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