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J Hazard Mater. 2013 Nov 15;262:64-70. doi: 10.1016/j.jhazmat.2013.08.034. Epub 2013 Aug 21.

Multilayer films of layered double hydroxide/polyaniline and their ammonia sensing behavior.

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  • 1State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, P.O. Box 98, Beijing 100029, PR China.

Abstract

This paper reports the fabrication of layered double hydroxide (LDH)/conductive polymer multilayer films by alternate assembly of exfoliated ZnAl-LDH nanosheets and polyaniline (PANI) on silicon wafer substrates using the layer-by-layer (LBL) deposition technology. UV-vis absorption spectroscopy indicates a stepwise and regular growth of the (LDH/PANI)n multilayer films upon increasing deposition cycles. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) demonstrate that the surfaces of the films are microscopy smooth and uniform with a thickness of 2 nm per bilayer. Furthermore, the resulting (LDH/PANI)n multilayer films possess high selectively response to ammonia at room temperature. The presence of LDH nanosheets plays a critical role on the gas sensing for the pure PANI film has very low response to ammonia. The LBL assembly process based on LDH combines the conducting polymer and nano-inorganic material, which provides opportunities to develop new inorganic-organic films for gas sensing.

Copyright © 2013 Elsevier B.V. All rights reserved.

KEYWORDS:

Ammonia sensing; Layer-by-layer; Layered double hydroxide; Polyaniline

PMID:
24012961
[PubMed - indexed for MEDLINE]
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