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Adv Mater. 2013 Sep 20;25(35):4912-7. doi: 10.1002/adma.201301513. Epub 2013 Jul 17.

Bio-inspired high-performance and recyclable cross-linked polymers.

Author information

  • 1Key Laboratory of Functional Polymer Materials of MOE, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, P. R. China.

Abstract

Bio-inspired molecular design and synthesis of high-performance and recyclable cross-linked polymers is reported. Reversible cross-links between hard segments are incorporated into linear segmented polyurethane via Diels-Alder reaction between maleimide pendant group and furan cross-linker. The materials form hierarchical structure and exhibit excellent properties with high stiffness, strength and toughness, and can be easily thermally reshaped and re-mended.

Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KEYWORDS:

Diels-Alder reaction; cross-link; high-performance; polyurethane; recyclability

PMID:
23861235
[PubMed - indexed for MEDLINE]
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