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J Am Chem Soc. 2013 Jul 17;135(28):10326-9. doi: 10.1021/ja4055492. Epub 2013 Jul 9.

Pd(II)-catalyzed C-H iodination using molecular I2 as the sole oxidant.

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  • 1Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.


Pd-catalyzed ortho-C-H iodination directed by a weakly coordinating amide auxiliary using I2 as the sole oxidant was developed. This reaction is compatible with a wide range of heterocycles including pyridines, imidazoles, oxazoles, thiazoles, isoxazoles, and pyrazoles.

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