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Chem Commun (Camb). 2013 Nov 14;49(88):10352-4. doi: 10.1039/c3cc43571g.

A C(3)-symmetric chiroptical molecular propeller based on hexakis(phenylethynyl)benzene with a threefold terephthalamide: stereospecific propeller generation through the cooperative transmission of point chiralities on the host and guest upon complexation.

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  • 1School of Materials Science, Japan Advanced Institute of Science and Technology, Nomi, Ishikawa 923-1292, Japan.

Abstract

Propeller-shaped dynamic helicity was generated in a hexakis(phenylethynyl)benzene framework that preferred a particular sense to afford a strong CD signal, which was realized by the cooperative transmission of point chiralities upon complexation with a chiral guest through a threefold binding site presented by a syn-formed terephthalamide.

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