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Inorg Chem. 2013 Jul 1;52(13):7314-6. doi: 10.1021/ic400986y. Epub 2013 Jun 7.

End-on azido-bridged 3d-4f complexes showing single-molecule-magnet property.

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  • 1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.

Abstract

Four tetranuclear 3d-4f complexes with the 4f centers bridged solely by end-on azide bridges were reported. The [CuTb]2 compound displays single-molecule-magnet behavior with hysteresis loops observed at up to 2.4 K.

PMID:
23746362
[PubMed]
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