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Org Lett. 2013 Jun 7;15(11):2692-5. doi: 10.1021/ol4009987. Epub 2013 May 17.

Palladium-catalyzed C-H arylation using phosphoramidate as a directing group at room temperature.

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  • 1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.

Abstract

This communication describes the first phosphoramidate directing group for synthetically useful arylation. Remarkably, the nature of a new directing group drives selective C-H bond activation to afford diverse N-aryl phosphoramidates in good to excellent yields at room temperature.

PMID:
23683086
[PubMed]
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