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Dalton Trans. 2013 Jun 28;42(24):8553-7. doi: 10.1039/c3dt50348h. Epub 2013 May 15.

Dimeric copper(II) complex of a new Schiff base ligand: effect of morphology on the catalytic oxidation of aromatic alcohol.

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  • 1Department of Chemistry, University of Delhi, Delhi-110007, India.

Abstract

An antiferromagnetically coupled, dimeric μ-naphthanoxo bridged copper(II) complex is used heterogeneously to catalyze oxidation of p-chlorobenzylalcohol to aldehyde selectively. PL and PXRD studies reveal that during recycling the catalyst remains essentially intact. However loss of catalytic efficiency upon reuse is in consonance with a loss in morphology as indicated by SEM.

PMID:
23673819
[PubMed]
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