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Org Biomol Chem. 2013 Jun 14;11(22):3612-5. doi: 10.1039/c3ob40429c.

Catalyst-controlled switchable phosphination of α-diazoesters.

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  • 1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China.


Organocatalyst and metal provide different products: a catalyst-controlled switchable phosphination of α-diazoesters has been developed by using DBU and copper as catalysts. It provided an efficient synthetic method for the construction of various phosphorus compounds via the formation of N-P and C-P bonds.

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