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Org Lett. 2013 May 17;15(10):2330-3. doi: 10.1021/ol400818v. Epub 2013 Apr 26.

Highly selective β-hydride elimination in Pd-catalyzed decarboxylative Heck-type reaction.

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  • 1School of Chemistry and Chemical Engineering, South China University of Technology , Guangzhou 510640, P. R. China.

Abstract

A variety of β-aryl ketones and aldehydes were facilely synthesized via a Pd(II)/Ag2CO3-mediated decarboxylative Heck type reaction between readily available benzoic acid derivatives and allylic alcohols under mild conditions. The control experiments indicated that this transformation may proceed via a hydrogen migration process.

PMID:
23621714
[PubMed]
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