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J Org Chem. 2013 Apr 19;78(8):4145-52. doi: 10.1021/jo400658d. Epub 2013 Apr 10.

C(sp3)-H bond arylations catalyzed by well-defined [Ru(O2CMes)2(p-cymene)].

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  • 1Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany.

Abstract

The well-characterized ruthenium(II) biscarboxylate complex [Ru(O2CMes)2(p-cymene)] enabled versatile direct (hetero)arylations of C(sp(3))-H bonds with low (co)catalyst loading and ample substrate scope. Detailed mechanistic studies provided strong support for a facile and reversible C(sp(3))-H bond metalation.

PMID:
23574572
[PubMed]
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