A tandem device which integrates a PVDF nanogenerator and silicon (Si) nanopillar solar cell is fabricated. The Si nanopillar solar cell was fabricated using a mask-free plasma etching technique and annealing process. The PVDF nanogenerator was stacked on top of the Si nanopillar solar cell using a spinning method. The optical properties and the device performance of nanowire solar cells have been characterized, and the dependence of device performance versus annealing time or method has been investigated. Furthermore, the PVDF nanogenerator was operated with a 100 dB sound wave and a 0.8 V peak to peak output voltage was generated. This tandem device can successfully harvest energy from both sound vibration and solar light, demonstrating its strong potential as a future ubiquitous energy harvester.