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Dalton Trans. 2013 Jun 7;42(21):7693-8. doi: 10.1039/c3dt50273b.

Slow magnetic relaxation in a cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain.

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  • 1Chemistry College, Dalian University of Technology, Dalian 116024, China.

Abstract

A cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain {[Fe(pzTp)(CN)3][Ni(chxn)2]}·ClO4·H2O (1) (pzTp = tetrakis(pyrazolyl)borate, chxn = (1R,2R)-1,2-diaminocyclohexane) was synthesized via rational design. Crystal structure analysis and magnetic studies demonstrated that compound had a one-dimensional zigzagging chain-like structure and slow magnetic relaxation.

PMID:
23538689
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