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Chemistry. 2013 May 10;19(20):6234-8. doi: 10.1002/chem.201300702. Epub 2013 Mar 22.

Enantioselective relay catalytic cascade intramolecular hydrosiloxylation and Mukaiyama aldol reaction.

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  • 1Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, PR China.


Cascading chemistry! The first practical relay catalytic cascade intramolecular hydrosiloxylation of arylacetylene and asymmetric Mukaiyama aldol reaction has been established to give synthetically useful products in high yields and with excellent ee (see scheme).

Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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