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Angew Chem Int Ed Engl. 2013 Apr 22;52(17):4645-9. doi: 10.1002/anie.201300759. Epub 2013 Mar 20.

Selective palladium-catalyzed hydroformylation of alkynes to α,β-unsaturated aldehydes.

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  • 1Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

Abstract

Atom-efficient: A selective palladium catalyst system is used for the hydroformylation of alkynes (see picture). In this syngas reaction, various alkynes were smoothly transformed to synthetically interesting α,β-unsaturated aldehydes in good yields with high regio- and stereoselectivity.

Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

PMID:
23520060
[PubMed]
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