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Sci Rep. 2013;3:1503. doi: 10.1038/srep01503.

Chlorine as an indicator in the controllable preparation of active nano-gold catalyst.

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  • 1Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China.

Abstract

The controllable preparation of nano-gold catalyst maintains a challenge. Except the parameters have been revealed before, here we'd like to show that controllable preparation of active nano-gold catalyst can be achieved using chlorine as an indicator. By tracing the chlorine concentration in the washing step, a series of Au/Fe2O3 catalysts were prepared with co-precipitation method. The applying of these catalysts in CO oxidation and reductive nitrobenzene N-alkylation suggested the active catalysts were prepared from solutions containing ~2 ppm chlorine. The catalytic activity dropped dramatically if the chlorine concentration is >4-6 or ≪1 ppm. Extensive characterizations revealed that the active catalyst was composed by nano-gold on the edge of Fe2O3 particle with 8.92 Au-Au coordination numbers. Although the real role of chlorine in the variation of catalyst structure and activity was still ambiguous, the current results should promote the controllable preparation of active nano-Au catalyst.

PMID:
23511444
[PubMed]
PMCID:
PMC3603287
Free PMC Article
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