Observation of a Burstein-Moss shift in rhenium-doped MoS2 nanoparticles

ACS Nano. 2013 Apr 23;7(4):3506-11. doi: 10.1021/nn400464g. Epub 2013 Mar 19.

Abstract

We investigated the optical properties of rhenium-doped MoS2 nanoparticles and compared our findings with the pristine and bulk analogues. Our measurements reveal that confinement softens the exciton positions and reduces spin-orbit coupling, whereas doping has the opposite effect. We model the carrier-induced exciton blue shift in terms of the Burstein-Moss effect. These findings are important for understanding doping and finite length scale effects in low-dimensional nanoscale materials.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Crystallization / methods
  • Light
  • Materials Testing
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure*
  • Molybdenum / chemistry*
  • Particle Size
  • Refractometry
  • Rhenium / chemistry*
  • Scattering, Radiation
  • Sulfides / chemistry*
  • Surface Properties

Substances

  • Sulfides
  • Rhenium
  • Molybdenum