Format

Send to:

Choose Destination
See comment in PubMed Commons below
Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1496. doi: 10.1107/S1600536812045473. Epub 2012 Nov 17.

Bis[2-({[2-(methyl-sulfan-yl)phen-yl]imino}-meth-yl)phenolato-κ(2) N,O]zinc chloro-form disolvate.

Author information

  • 1Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 807, Taiwan.

Abstract

The monomeric title complex, [Zn(C14H12NOS)2]·2CHCl3 or L2Zn·2CHCl3, where L is the 2-({[2-(methyl-sulfan-yl)phen-yl]imino}-meth-yl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt2 in tetra-hydro-furan. The Zn atom, located on a twofold axis, is four-coordinated in a distorted tetra-hedral geometry by two O atoms [Zn-O = 1.9472 (19) Å] from the phenolate anions and two imine N atoms [Zn-N = 2.054 (2) Å].

PMID:
23468714
[PubMed]
PMCID:
PMC3588749
Free PMC Article
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for PubMed Central
    Loading ...
    Write to the Help Desk