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Chem Commun (Camb). 2013 Apr 4;49(26):2682-4. doi: 10.1039/c3cc39286d.

Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions.

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  • 1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 RenAi Road, Suzhou 215123, Jiangsu, PR China.

Abstract

The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]n produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]n through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]┬ĚH2O}n in which HT-ppcb underwent in situ oxidation to form a unique furan-based ligand bpbpf.

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