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Chemistry. 2013 Mar 18;19(12):3817-21. doi: 10.1002/chem.201203800. Epub 2013 Feb 18.

Poly(ethylene glycol) as a reaction matrix in platinum- or gold-catalyzed cycloisomerization: a mechanistic investigation.

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  • 1Institut des Biomolécules Max Mousseron (IBMM), CNRS-Université Montpellier I et 2, Place E. Bataillon, 34095 Montpellier Cedex 5, France.


Design for diversity: A new catalytic system based on PEG-3400 and a metal salt (Pt or Au) was designed to efficiently perform a cycloisomerization reaction under microwave irradiation, which gave diverse heterocycles in good to excellent yields, after a precipitation/filtration procedure (see scheme).

Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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