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Org Lett. 2013 Feb 15;15(4):808-11. doi: 10.1021/ol303484f. Epub 2013 Jan 30.

Facile synthesis of 2-arylphenols via palladium-catalyzed cross-coupling of aryl iodides with 6-diazo-2-cyclohexenones.

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  • 1State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China.


2-Arylphenols were conveniently synthesized from aryl iodides and 6-diazo-2-cyclohexenones, in moderate to excellent yields, via tandem Pd-catalyzed cross-coupling/aromatization. The preliminary results for the corresponding enantioselective version showed that the coupling products could be generated in up to 72% ee.

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