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J Am Chem Soc. 2013 Feb 13;135(6):2092-5. doi: 10.1021/ja311968d. Epub 2013 Jan 31.

Iridium-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes via C-H activation.

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  • 1Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan. tnishi@kuchem.kyoto-u.ac.jp

Abstract

Ir-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes, in which an aryliridium intermediate is formed via C-H activation, gives aminoindane derivatives in high yields with high regio- and diastereoselectivity.

PMID:
23351145
[PubMed - indexed for MEDLINE]
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