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Chem Commun (Camb). 2013 Feb 25;49(16):1624-6. doi: 10.1039/c3cc38260e.

A charge-polarized porous metal-organic framework for gas chromatographic separation of alcohols from water.

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  • 1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, P. R. China.


A bipyridinium ligand with a charge separated skeleton has been introduced into a metal-organic framework to yield a porous material with charge-polarized pore space, which exhibits selective adsorption for polar guest molecules and can be further used in gas chromatography for the separation of alcohol-water mixtures.

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