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Chem Commun (Camb). 2013 Feb 21;49(15):1509-11. doi: 10.1039/c3cc38073d.

Coordinative trapping of the boron β-diketiminato system [B(NMesCMe)2CH] via metal-templated synthesis.

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  • 1Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Rd, Oxford, UK OX1 3QR.


A metal templated synthetic approach gives access to [Cp*Fe(CO)(2){B(NMesCMe)(2)CH}][BAr(f)(4)], and represents the first example of coordinative trapping of the elusive [B(NRCMe)(2)CH] fragment.

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