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Chem Commun (Camb). 2013 Feb 18;49(14):1395-7. doi: 10.1039/c2cc38227j.

Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand.

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  • 1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.

Abstract

Deep-cavity cavitand TEMOA (2) is shown to assemble via the hydrophobic effect into tetrameric and hexameric assemblies. With inner volumes of 1400-1500 Å(3) and 3200-3700 Å(3) respectively, these well-defined and mono-dispersed assemblies represent the largest of their type to date.

PMID:
23306216
[PubMed]
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