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Org Lett. 2013 Jan 4;15(1):132-5. doi: 10.1021/ol303157b. Epub 2012 Dec 19.

Total syntheses of (±)-α-lycorane and (±)-1-deoxylycorine.

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  • 1Department of Chemistry, Hanyang University, Seoul 133-791, Korea.

Abstract

New synthetic routes to (±)-α-lycorane and (±)-1-deoxylycorine were exploited. The endo-cycloadduct of 3,5-dibromo-2-pyrone with styrene-type dienophile provided the pivotal intermediate for the syntheses of the titled natural products.

PMID:
23252961
[PubMed - indexed for MEDLINE]
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