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Dalton Trans. 2013 Jan 7;42(1):67-70. doi: 10.1039/c2dt32009f.

Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers.

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  • 1Chemistry Research Laboratory and University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK.

Abstract

Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

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