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Org Biomol Chem. 2012 Sep 7;10(33):6767-75. doi: 10.1039/c2ob25662b. Epub 2012 Jul 19.

Improving the carboxyamidomethyl ester for subtilisin A-catalysed peptide synthesis.

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  • 1Institute for Molecules and Materials, Radboud University Nijmegen, The Netherlands.


A series of novel glycine esters was evaluated for efficiency in subtilisin A-CLEA-catalysed peptide synthesis. The reactivity of the easily accessible carboxyamidomethyl (Cam) ester was further enhanced by elongating it with an amino acid residue, thereby creating more recognition space for subtilisin A.

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