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Chem Asian J. 2012 Nov;7(11):2562-8. doi: 10.1002/asia.201200309. Epub 2012 Jul 16.

Towards a zinc-catalyzed asymmetric hydrogenation/transfer hydrogenation of imines.

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  • 1Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany.

Abstract

The first asymmetric hydrogenation/transfer hydrogenation of imines to amines using zinc(II) triflate in combination with chiral ligands is described. The monodentate binaphthophosphepine ligand (3 g) provided the highest enantioselectivities. Using different imines, the corresponding amines were obtained in moderate yields and enantioselectivities.

Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

PMID:
22807402
[PubMed - indexed for MEDLINE]
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