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Angew Chem Int Ed Engl. 2012 Jul 27;51(31):7781-5. doi: 10.1002/anie.201202337. Epub 2012 Jun 22.

Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination.

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  • 1Department of Chemistry and Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu 30013, Taiwan.

Abstract

Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr(I) and Cr(II)), which are important species in the formation of type I quintuple-bonded complexes.

Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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