Chemistry. 2012 Jul 16;18(29):8886-90. doi: 10.1002/chem.201201474. Epub 2012 Jun 19.

Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: carbocyclic ligands as scaffolds for a mixed-metal system.

Murahashi T, Usui K, Tachibana Y, Kimura S, Ogoshi S.

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Institute for Molecular Science, Okazaki, Aichi, 444-8787, Japan. mura@ims.ac.jp

Abstract

Sandwich time! The mixed-metal triangular-trinuclear sandwich complexes of Pd(2)Pt and PdPt(2) were selectively synthesized. The Pd(2)Pt and PdPt(2) triangles in a cycloheptatrienyl sandwich framework were identified by (31)P NMR analyses of the tris-triphenylphosphine complexes (see scheme).

PMID:: 22714664; [PubMed]

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Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: car...
Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: carbocyclic ligands as scaffolds for a mixed-metal system.
Chemistry. 2012 Jul 16 ;18(29):8886-90. doi: 10.1002/chem.201201474. Epub 2012 Jun 19 .

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Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: carbocyclic ligands as scaffolds for a mixed-metal system.

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