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Chemistry. 2012 Jul 16;18(29):8886-90. doi: 10.1002/chem.201201474. Epub 2012 Jun 19.

Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: carbocyclic ligands as scaffolds for a mixed-metal system.

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  • 1Institute for Molecular Science, Okazaki, Aichi, 444-8787, Japan.


Sandwich time! The mixed-metal triangular-trinuclear sandwich complexes of Pd(2)Pt and PdPt(2) were selectively synthesized. The Pd(2)Pt and PdPt(2) triangles in a cycloheptatrienyl sandwich framework were identified by (31)P NMR analyses of the tris-triphenylphosphine complexes (see scheme).

Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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