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Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1071. doi: 10.1107/S1600536812010513. Epub 2012 Mar 14.

4-Fluoro-2-[(3-methyl-phen-yl)imino-meth-yl]phenol.

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  • 1Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.

Abstract

The title compound, C(14)H(12)FNO, crystallizes as the trans phenol-imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra-molecular O-H⋯N hydrogen bond between the hy-droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C-H⋯O and C-H⋯F inter-actions, which link the mol-ecules into a stable three-dimensional network.

PMID:
22589937
[PubMed]
PMCID:
PMC3344028
Free PMC Article

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