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Top Curr Chem. 2013;335:157-200. doi: 10.1007/128_2011_312.

Paramagnetic solid-state magic-angle spinning NMR spectroscopy.

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  • 1Centre de RMN à Très Hauts Champs, Institut de Sciences Analytiques, Université de Lyon, UMR 5280 CNRS/Ecole Normale Supérieure de Lyon/Université Claude Bernard Lyon 1, 69100, Villeurbanne, France, guido.pintacuda@ens-lyon.fr.

Abstract

A number of technical improvements have recently opened up solid-state NMR to the analysis of new classes of substrates with wide ranging implications for molecular and biological sciences, with an immediate impact on a large community of researchers. A wealth of information can be extracted from the analysis of solid-state NMR signals of paramagnetic compounds, as the changes induced by the paramagnetic center depend in a well-defined way on the structure of the molecule. Solid-state NMR is in a position to allow direct, straightforward experimental access to the fine details of the molecular electronic configuration, which is in turn a sensible reporter of the molecular geometry in small catalysts as well as in larger biomolecules.

PMID:
22392478
[PubMed - indexed for MEDLINE]
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