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Chem Commun (Camb). 2012 Mar 28;48(26):3209-11. doi: 10.1039/c2cc17276c. Epub 2012 Feb 13.

Influence of polymorphism on charge transport properties in isomers of fluorenone-based liquid crystalline semiconductors.

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  • 1CEA-Grenoble, INAC, UMR5819-SPrAM (CEA-CNRS-Univ. J. Fourier-Grenoble 1), Laboratoire d'Electronique Mol√©culaire Organique et Hybride, 17 Rue des Martyrs, 38054 Grenoble Cedex 9, France.


We measured the charge carrier mobilities for two isomers of fluorenone-based liquid crystalline organic semiconductors from their isotropic down to crystalline states through one or two mesophases. Improved charge transport properties of melt-processed crystalline films were obtained for the isomer exhibiting a highly ordered mesophase below its disordered smectic phase.

This journal is © The Royal Society of Chemistry 2012

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