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Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1072. doi: 10.1107/S1600536811025335. Epub 2011 Jul 9.

Tetra-aqua-bis-[4-(4H-1,2,4-triazol-4-yl)benzoato-κN]manganese(II) deca-hydrate.

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  • 1Department of Laboratory and Equipment Management, Yanbian University, Yanbian 133002, People's Republic of China.

Abstract

In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol-ecules in a distorted octa-hedral geometry. The Mn(II) ion and two coordinated water mol-ecules lie on a twofold rotation axis. The water mol-ecules are involved in O-H⋯N and O-H⋯O hydrogen bonds with the triazole N atoms and carboxyl-ate O atoms, yielding a three-dimensional supra-molecular network. π-π inter-actions between the benzene rings [centroid-centroid distance = 3.836 (9) Å] are observed.

PMID:
22090852
[PubMed]
PMCID:
PMC3212150
Free PMC Article
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