Synthesis and structural characterization of an unprecedented nonmetal cation polyborate salt containing two different "isolated" polyborate anions: [H2en]2[B4O5(OH)4][B7O9(OH)5]·3H2O (en = H2NCH2CH2NH2)

Michael A Beckett; Peter N Horton; Simon J Coles; David W Martin

doi:10.1021/ic202144f

Synthesis and structural characterization of an unprecedented nonmetal cation polyborate salt containing two different "isolated" polyborate anions: [H2en]2[B4O5(OH)4][B7O9(OH)5]·3H2O (en = H2NCH2CH2NH2)

Inorg Chem. 2011 Dec 5;50(23):12215-8. doi: 10.1021/ic202144f. Epub 2011 Nov 3.

Authors

Michael A Beckett¹, Peter N Horton, Simon J Coles, David W Martin

Affiliation

¹ School of Chemistry, Bangor University, Bangor, Gwynedd, UK, LL57 2UW. m.a.beckett@bangor.ac.uk

PMID: 22050277
DOI: 10.1021/ic202144f

Abstract

The nonmetal cation polyborate salt of stoichiometry [H(2)en](2)[B(11)O(18)(OH)]·7H(2)O is obtained from the reaction of 1,2-diaminoethane and boric acid (1:5 ratio) in H(2)O/MeOH. An X-ray crystallographic study of the product reveals that the polyborate moiety is composed of two isolated hydrated polyborate anions: [B(4)O(5)(OH)(4)](2-) and [B(7)O(9)(OH)(5)](2-). The structure is templated by the cations with the anions forming a supramolecular H-bonded network, augmented by additional H-bonds involving the waters of crystallization and the cations.