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Nano Lett. 2011 Dec 14;11(12):5367-72. doi: 10.1021/nl202950h. Epub 2011 Nov 7.

Mapping nanomagnetic fields using a radical pair reaction.

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  • 1Department of Chemistry and Chemical Biology, School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, United States.

Abstract

We used a fluorescent chemical indicator of magnetic field to visualize the magnetic field around ferromagnetic nanostructures. The indicator was a chain-linked electron donor-acceptor molecule, phenanthrene-(CH2)12-O-(CH2)2-dimethylaniline, that forms spin-correlated radical pairs upon photoexcitation. The magnetic field altered the coherent spin dynamics, yielding an 80% increase in exciplex fluorescence in a 0.1 T magnetic field. The magnetic field distributions were quantified to precision of 1.8×10(-4) T by image analysis and agreed with finite-element nanomagnetic simulations.

PMID:
22044347
[PubMed - indexed for MEDLINE]
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