Abstract
The neutral complex [PtCl(PyDT)](5) (PyDT = (CH(2))(4)NCS(2)(-)) represents the first example of a Pt(5) metallacycle. This unique architecture based on chiral S-bridged Pt(II) monomers was prepared by thermal degradation of the reaction product of PtCl(2) and a pyrrolidinedithioester.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Coordination Complexes / chemistry*
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Crystallography, X-Ray
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Molecular Conformation
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Platinum / chemistry*
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Pyrrolidines / chemistry*
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Stereoisomerism
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Thiocarbamates / chemistry*
Substances
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Coordination Complexes
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Pyrrolidines
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Thiocarbamates
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pyrrolidine dithiocarbamic acid
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Platinum