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Org Biomol Chem. 2011 Sep 7;9(17):6022-6. doi: 10.1039/c1ob05726j. Epub 2011 Jul 20.

Synthesis of a [2]rotaxane operated in basic environment.

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  • 1Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P.R. China.

Abstract

A tight [2]rotaxane with two chromophores as stoppers is described, in which the macrocycle is able to reversibly move by tuning of base. This moving process can result in intramolecular photo-induced electron transfer (PET), changing the photo-physical properties.

PMID:
21773625
[PubMed]
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