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Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m482. doi: 10.1107/S1600536811010385. Epub 2011 Mar 26.

[N'-(3,5-Diiodo-2-oxidobenzyl-idene-κO)-4-methyl-benzohydrazidato-κN',O](methanol-κO)(methano-lato-κO)oxidovanadium(V).

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  • College of Chemistry and Biology Engineering, Yichun University, Yichun 336000, People's Republic of China.

Abstract

In the title mol-ecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N'-(3,5-diiodo-2-oxidobenzyl-idene-κO)-4-methyl-benzo-hydra-zidate (L) ligand, one oxide O atom, one methano-late [V-O = 1.761 (3) Å] and one methanol [V-O = 2.383 (4) Å] O atom in a distorted octa-hedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)°. In the crystal, inter-molecular O-H⋯N hydrogen bonds link pairs of mol-ecules into centrosymmetric dimers which exhibit π-π inter-actions between the aromatic rings [centroid-centroid distance = 3.677 (5) Å].

PMID:
21753994
[PubMed]
PMCID:
PMC3100050
Free PMC Article

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