Two-dimensional assembly of [Mn(III)₂Mn(II)₂] single-molecule magnets and [Cu(pic)₂] linking units (Hpic = picolinic acid)

Ie-Rang Jeon; Rodica Ababei; Lollita Lecren; Yang-Guang Li; Wolfgang Wernsdorfer; Olivier Roubeau; Corine Mathonière; Rodolphe Clérac

doi:10.1039/c000311e

Two-dimensional assembly of [Mn(III)₂Mn(II)₂] single-molecule magnets and [Cu(pic)₂] linking units (Hpic = picolinic acid)

Dalton Trans. 2010 May 28;39(20):4744-6. doi: 10.1039/c000311e.

Authors

Ie-Rang Jeon¹, Rodica Ababei, Lollita Lecren, Yang-Guang Li, Wolfgang Wernsdorfer, Olivier Roubeau, Corine Mathonière, Rodolphe Clérac

Affiliation

¹ CNRS, UPR 8641, Centre de Recherche Paul Pascal (CRPP), Equipe Matériaux Moléculaires Magnétiques, 115 avenue du Dr Albert Schweitzer, Pessac, F-33600, France.

PMID: 21488317
DOI: 10.1039/c000311e

Abstract

In an attempt to develop novel coordination networks of SMMs, a Cu(II) picolinate complex has been used to coordinate S(T) = 9 tetranuclear Mn-based SMMs resulting in an intriguing 2D framework exhibiting a magnet-like behavior at low temperature.