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Dalton Trans. 2011 Apr 7;40(13):3125-7. doi: 10.1039/c0dt01712d. Epub 2011 Feb 24.

Access to an unusual Fe9 core topology from the initial use of tricine in iron(III) cluster chemistry.

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  • 1WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, UK G12 8QQ.


We describe an enneanuclear Fe(III) complex with an unusual boat-shaped core topology and an S=11/2 ground state, assembled using the ligands tricine {N-(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)glycine, H(4)L} and 2-phenoxybenzoate.

© The Royal Society of Chemistry 2011

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