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J Org Chem. 2011 Mar 4;76(5):1185-97. doi: 10.1021/jo1024738. Epub 2011 Jan 19.

Organoiodine(V) reagents in organic synthesis.

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  • 1Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota 55812, USA. vzhdanki@d.umn.edu

Abstract

Organohypervalent iodine reagents have attracted significant recent interest as versatile and environmentally benign oxidants with numerous applications in organic synthesis. This Perspective summarizes synthetic applications of hypervalent iodine(V) reagents: 2-iodoxybenzoic acid (IBX), Dess-Martin periodinane (DMP), pseudocyclic iodylarenes, and their recyclable polymer-supported analogues. Recent advances in the development of new catalytic systems based on the generation of hypervalent iodine species in situ are also overviewed.

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